Total Synthesis of Terpioside B

Kazuki Inaba, Masato Endo, Naoto Iibuchi, Daisuke Takahashi, Kazunobu Toshima

研究成果: Article査読

2 被引用数 (Scopus)

抄録

The first total synthesis of terpioside B (1) has been accomplished. Key steps include the stereoselective installments of a set of challenging 1,2-cis-glycosidic linkages. Thus, α(1,4)-linked d-galactoside was effectively constructed from a 1,2-anhydrogalactose donor and an unprotected 1,6-anhydrogalactose acceptor by using a boron-mediated aglycon delivery (BMAD) method. In addition, α-l-fucofuranosides were stereoselectively and simultaneously constructed by remote group-assisted 1,2-cis-α-stereoselective glycosylations.

本文言語English
ページ(範囲)10222-10225
ページ数4
ジャーナルChemistry - A European Journal
26
45
DOI
出版ステータスPublished - 2020 8 12

ASJC Scopus subject areas

  • 触媒
  • 有機化学

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