Trans-Bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato- κN3)copper(II) and its chloroform disolvate

Takashiro Akitsu, Yasuaki Einaga

研究成果: Article

19 引用 (Scopus)

抄録

The crystal structures of the title compounds, [Cu(C15H 11N2-O2)2(C14H 15N)2] and [Cu(C15H11N 2O2)2(C14H15N) 2]·2CHCl3, respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu" atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.

元の言語English
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
61
発行部数4
DOI
出版物ステータスPublished - 2005 4

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Chloroform
chloroform
Copper
Crystal structure
copper
crystal structure
Molecules
Dimers
assemblies
molecules
dimers
Atoms
symmetry
atoms

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

これを引用

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AB - The crystal structures of the title compounds, [Cu(C15H 11N2-O2)2(C14H 15N)2] and [Cu(C15H11N 2O2)2(C14H15N) 2]·2CHCl3, respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu" atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.

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