Transformation of Trifluorotoluenes Triggered by Titanium(IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes

Takayuki Yamada, Kodai Saito, Takahiko Akiyama

研究成果: Article

15 引用 (Scopus)

抜粋

The titanium tetrachloride-catalyzed hydrodefluorination reaction of trifluorotoluene derivatives was developed using triethylsilane as the reducing agent. The reaction produced various toluene derivatives with high chemoselectivities by means of readily accessible reagents. This hydrodefluorination process was extended to the intramolecular Friedel-Crafts benzylation reaction, furnishing polycyclic aromatics of various ring sizes in good yields.

元の言語English
ページ(範囲)62-66
ページ数5
ジャーナルAdvanced Synthesis and Catalysis
358
発行部数1
DOI
出版物ステータスPublished - 2016 1 7
外部発表Yes

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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