抄録
The titanium tetrachloride-catalyzed hydrodefluorination reaction of trifluorotoluene derivatives was developed using triethylsilane as the reducing agent. The reaction produced various toluene derivatives with high chemoselectivities by means of readily accessible reagents. This hydrodefluorination process was extended to the intramolecular Friedel-Crafts benzylation reaction, furnishing polycyclic aromatics of various ring sizes in good yields.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 62-66 |
| ページ数 | 5 |
| ジャーナル | Advanced Synthesis and Catalysis |
| 巻 | 358 |
| 号 | 1 |
| DOI | |
| 出版ステータス | Published - 2016 1月 7 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 触媒
- 有機化学