抜粋
The titanium tetrachloride-catalyzed hydrodefluorination reaction of trifluorotoluene derivatives was developed using triethylsilane as the reducing agent. The reaction produced various toluene derivatives with high chemoselectivities by means of readily accessible reagents. This hydrodefluorination process was extended to the intramolecular Friedel-Crafts benzylation reaction, furnishing polycyclic aromatics of various ring sizes in good yields.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 62-66 |
| ページ数 | 5 |
| ジャーナル | Advanced Synthesis and Catalysis |
| 巻 | 358 |
| 発行部数 | 1 |
| DOI | |
| 出版物ステータス | Published - 2016 1 7 |
| 外部発表 | Yes |
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
フィンガープリント Transformation of Trifluorotoluenes Triggered by Titanium(IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Yamada, T., Saito, K., & Akiyama, T. (2016). Transformation of Trifluorotoluenes Triggered by Titanium(IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes. Advanced Synthesis and Catalysis, 358(1), 62-66. https://doi.org/10.1002/adsc.201500920