Transformation of Trifluorotoluenes Triggered by Titanium(IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes

Takayuki Yamada, Kodai Saito, Takahiko Akiyama

研究成果: Article査読

21 被引用数 (Scopus)

抄録

The titanium tetrachloride-catalyzed hydrodefluorination reaction of trifluorotoluene derivatives was developed using triethylsilane as the reducing agent. The reaction produced various toluene derivatives with high chemoselectivities by means of readily accessible reagents. This hydrodefluorination process was extended to the intramolecular Friedel-Crafts benzylation reaction, furnishing polycyclic aromatics of various ring sizes in good yields.

本文言語English
ページ(範囲)62-66
ページ数5
ジャーナルAdvanced Synthesis and Catalysis
358
1
DOI
出版ステータスPublished - 2016 1 7
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 有機化学

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