Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

Naoyuki Furukawa; Noriko Kourogi; Yoshio Seki; Fumitoshi Kakiuchi; Shinji Murai

doi:10.1021/om990336l

Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

Naoyuki Furukawa, Noriko Kourogi, Yoshio Seki, Fumitoshi Kakiuchi, Shinji Murai

研究成果: Article › 査読

23 被引用数 (Scopus)

抄録

The catalyzed reaction of an excess of styrene with n-Bu₃GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU₃(CO)₁₂, whose use resulted in selective formation of the vinylgermanes in high yields.

本文言語	English
ページ（範囲）	3764-3767
ページ数	4
ジャーナル	Organometallics
巻	18
号	18
DOI	https://doi.org/10.1021/om990336l
出版ステータス	Published - 1999 8月 30
外部発表	はい

ASJC Scopus subject areas

物理化学および理論化学
有機化学
無機化学

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10.1021/om990336l

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author = "Naoyuki Furukawa and Noriko Kourogi and Yoshio Seki and Fumitoshi Kakiuchi and Shinji Murai",

year = "1999",

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doi = "10.1021/om990336l",

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AU - Furukawa, Naoyuki

AU - Kourogi, Noriko

AU - Seki, Yoshio

AU - Kakiuchi, Fumitoshi

AU - Murai, Shinji

PY - 1999/8/30

Y1 - 1999/8/30

N2 - The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU3(CO)12, whose use resulted in selective formation of the vinylgermanes in high yields.

AB - The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU3(CO)12, whose use resulted in selective formation of the vinylgermanes in high yields.

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Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

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