Transparent and luminescent thin films of partially substituted La10 (Si O4) 6 O3: Eu3+ apatite-type silicates

Yuichi Otsuka, Shinobu Fujihara

研究成果: Article査読

7 被引用数 (Scopus)

抄録

Partially substituted oxyapatite silicates, La8 M2 (Si O4) 6 O3: Eu3+ (M=Na, K, Mg, Ca, Sr, Y, and Gd), were prepared as powders and thin films by the conventional solid-state reaction and the sol-gel method, respectively. X-ray diffractometry and Fourier transform infrared spectroscopy were used to evaluate crystallinity and structure of the silicates. Transparent thin-film samples fabricated on quartz glass substrates exhibited intense red emissions due to Eu3+ upon irradiation with UV light through the charge-transfer excitation from O2- to Eu3+. The excitation wavelength, which was 268 nm for the nonsubstituted silicate, was shifted by the substitution in the host silicates. This shift was explained by the change in the lattice constant c and accordingly, the Eu-O distance. Our results then demonstrate that fine tuning of the excitation was possible in the chemically stable and transparent oxyapatite thin films.

本文言語English
ページ(範囲)J335-J340
ジャーナルJournal of the Electrochemical Society
154
10
DOI
出版ステータスPublished - 2007 8月 31

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

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