Polycrystalline samples of novel oxypnictides, Sr2ScMPO3, with MP layer (M Mn, Ni and Co0.5Fe0.5) were synthesized, and their resistivities and Seebeck coefficients were measured. Sr2ScMPO3 crystallizes in a stacked, layered structure comprised of a ThCr2Si2- type MP layer alternating with a K2NiF4-type Sr2ScO3 layer. Sr2ScMnPO3 is an insulator at room temperature. The resistivities (ρ) of Sr2ScNiPO3 and Sr2ScCo0.5Fe0.5PO3 decrease with decreasing temperature like a metal. The Seebeck coefficients (S) of these materials are negative at room temperature. For Sr2ScNiPO3, S initially decreases slightly with decreasing temperature, and increases with decreasing temperature below 50 K. However, for Sr2ScCo0.5Fe0.5PO3, S increases with decreasing temperature, and attains to a positive value below 270 K.
|ジャーナル||Journal of Physics: Conference Series|
|出版ステータス||Published - 2014|
|イベント||27th International Conference on Low Temperature Physics, LT 2014 - Buenos Aires, Argentina|
継続期間: 2014 8月 6 → 2014 8月 13
ASJC Scopus subject areas