Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines

Daisuke Takahashi, Koji Nakabayashi, Shu Tanaka, Shin Ichi Ohkoshi

研究成果: Article査読

6 被引用数 (Scopus)

抄録

We report the crystal structure and magnetic properties of a two-dimensional cyano-bridged MnII(S = 5/2)-NbIV(S = 1/2) bimetal assembly (1), and the magnetic properties of an isostructural cyano-bridged MnII-MoIV(S = 0) bimetal assembly (2). 1 contains 3-hydroxypyridine ligands with four types of coordination arrangements, includes μ-oxo-bridged Mn-Mn sites, and shows ferrimagnetism with a Curie temperature of 16 K due to the antiferromagnetic MnII-NbIV superexchange interaction through the cyano groups. 2 exhibits paramagnetism with the antiferromagnetic interaction between Mn and Mn through the μ-oxo-bridges.

本文言語English
ページ(範囲)47-50
ページ数4
ジャーナルInorganic Chemistry Communications
27
DOI
出版ステータスPublished - 2013 1
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

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