Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Yujiro Hayashi, Mitsuhiro Takeda, Mitsuru Shoji, Masataka Morita

研究成果: Article査読

抄録

Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl3 two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.

本文言語English
ページ(範囲)68-69
ページ数2
ジャーナルChemistry Letters
36
1
DOI
出版ステータスPublished - 2007 1月 5

ASJC Scopus subject areas

  • 化学 (全般)

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