抄録
Adsorption of CO on Cs-precovered Ru(001) with one-monolayer coverage (θCs = 0.33) has been investigated by use of electron energy loss spectroscopy (EELS), temperature-programmed desorption (TPD), and low-energy electron diffraction (LEED). The C-O stretching mode of the adsorbed CO does not appear in the specular mode of EELS but clearly appears in the off-specular mode at an unusually low frequency of 1245 cm-1. This unusual adsorption state has been interpreted in terms of an inclined or a side-on adsorption geometry of CO and formation of a double-layer structure (Cs/Cs + CO/Ru(001)) where the CO dipole is screened by the second-layer Cs.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 390-392 |
| ページ数 | 3 |
| ジャーナル | Journal of Physical Chemistry |
| 巻 | 98 |
| 号 | 2 |
| DOI | |
| 出版ステータス | Published - 1994 1月 1 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 工学（全般）
- 物理化学および理論化学