Unusual electronic structure of bis-isocyanide complexes of iron(iii) porphyrinoids

Yoshiki Ohgo, Saburo Neya, Daisuke Hashizume, Tomoji Ozeki, Mikio Nakamura

研究成果: Article査読

4 被引用数 (Scopus)

抄録

A series of isocyanide complexes, [Fe(Porphyrinoid)( tBuNC) 2] +, were synthesized and examined for their physicochemical properties. The molecular structure of the bis( tBuNC) adduct of the iron(iii) porphycene (1) and corrphycene (2) adopting the (d xy) 2(d xz, d yz) 3 ground state were determined for the first time. Furthermore, 1 and 2 showed unusual crossover phenomena between different electron configurations, (d xy) 2(d xz, d yz) 3 ground state and (d xz, d yz) 4(d xy) 1 ground state, by the addition of the external stimuli.

本文言語English
ページ(範囲)3126-3129
ページ数4
ジャーナルDalton Transactions
41
11
DOI
出版ステータスPublished - 2012 3 21

ASJC Scopus subject areas

  • 無機化学

フィンガープリント

「Unusual electronic structure of bis-isocyanide complexes of iron(iii) porphyrinoids」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル