抄録
A series of isocyanide complexes, [Fe(Porphyrinoid)( tBuNC) 2] +, were synthesized and examined for their physicochemical properties. The molecular structure of the bis( tBuNC) adduct of the iron(iii) porphycene (1) and corrphycene (2) adopting the (d xy) 2(d xz, d yz) 3 ground state were determined for the first time. Furthermore, 1 and 2 showed unusual crossover phenomena between different electron configurations, (d xy) 2(d xz, d yz) 3 ground state and (d xz, d yz) 4(d xy) 1 ground state, by the addition of the external stimuli.
本文言語 | English |
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ページ(範囲) | 3126-3129 |
ページ数 | 4 |
ジャーナル | Dalton Transactions |
巻 | 41 |
号 | 11 |
DOI | |
出版ステータス | Published - 2012 3月 21 |
外部発表 | はい |
ASJC Scopus subject areas
- 無機化学