Use of perfluorocarboxylic acids to trick cytochrome P450BM3 into initiating the hydroxylation of gaseous alkanes

Norifumi Kawakami, Osami Shoji, Yoshihito Watanabe

研究成果: Article

75 引用 (Scopus)

抜粋

It has long been believed that the fatty acid hydroxylase wild-type P450BM3 is unable to oxidize gaseous alkanes. However, the simple addition of a perfluorocarboxylic acid as a dummy substrate to initiate the P450BM3 catalytic cycle enabled the efficient hydroxylation of butane and propane (see picture).

元の言語English
ページ(範囲)5315-5318
ページ数4
ジャーナルAngewandte Chemie - International Edition
50
発行部数23
DOI
出版物ステータスPublished - 2011 5 27

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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