Utilisation of L-quebrachitol in natural product synthesis. Total synthesis and absolute configuration of (-)-oudemansin X

Noritaka Chida; Ken Yamada; Seiichiro Ogawa

Utilisation of L-quebrachitol in natural product synthesis. Total synthesis and absolute configuration of (-)-oudemansin X

Noritaka Chida, Ken Yamada, Seiichiro Ogawa

応用化学科

研究成果: Article › 査読

18 被引用数 (Scopus)

抄録

The stereoselective conversion of the naturally occurring optically active cyclitol, L-quebrachitol 2, into antifungal β-methoxyacrylate, oudemansin X 1 is described. This first total synthesis of 1 fully confirmed the proposed absolute configuration of the antibiotic and showed the importance of 2 as a versatile chiral starting material in natural product syntheses.

本文言語	English
ページ（範囲）	1957-1962
ページ数	6
ジャーナル	Journal of the Chemical Society, Perkin Transactions 1
号	17
出版ステータス	Published - 1993 12月 1

ASJC Scopus subject areas

化学 (全般)

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引用スタイル

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abstract = "The stereoselective conversion of the naturally occurring optically active cyclitol, L-quebrachitol 2, into antifungal β-methoxyacrylate, oudemansin X 1 is described. This first total synthesis of 1 fully confirmed the proposed absolute configuration of the antibiotic and showed the importance of 2 as a versatile chiral starting material in natural product syntheses.",

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N2 - The stereoselective conversion of the naturally occurring optically active cyclitol, L-quebrachitol 2, into antifungal β-methoxyacrylate, oudemansin X 1 is described. This first total synthesis of 1 fully confirmed the proposed absolute configuration of the antibiotic and showed the importance of 2 as a versatile chiral starting material in natural product syntheses.

AB - The stereoselective conversion of the naturally occurring optically active cyclitol, L-quebrachitol 2, into antifungal β-methoxyacrylate, oudemansin X 1 is described. This first total synthesis of 1 fully confirmed the proposed absolute configuration of the antibiotic and showed the importance of 2 as a versatile chiral starting material in natural product syntheses.

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Utilisation of L-quebrachitol in natural product synthesis. Total synthesis and absolute configuration of (-)-oudemansin X

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ASJC Scopus subject areas

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