TY - JOUR
T1 - Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser
AU - Sugawara, M.
AU - Yamamoto, K.
AU - Fujimura, Y.
PY - 1994/1/1
Y1 - 1994/1/1
N2 - Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.
AB - Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.
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U2 - 10.1016/S0022-2860(10)80058-4
DO - 10.1016/S0022-2860(10)80058-4
M3 - Article
AN - SCOPUS:84912993996
SN - 0022-2860
VL - 310
SP - 77
EP - 82
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
ER -